1. Minister Mr.Geng Biao (1951.03-1954.09)

2. H.E. Ambassador Mr.Chen Xinren (1954.10-1958.11)

3. H.E. Ambassador Mr. Gan Yetao (1959.02-1962.06)

4. H.E. Ambassador Mr. Zhang Bochuan (1962.08-1965.07)

5. H.E. Ambassador Mr. Yue Xin (1965.08-1967.01)

6. H.E. Ambassador Mr. Shi Ziming (1970.04-1975.07)

7. H.E. Ambassador Mr. Zhang Canming (1975.09-1978.11)

8. H.E. Ambassador Mr. Xie Bangzhi (1979.03-1980.04)

9. H.E. Ambassador Mr. Sun Shengwei (1981.05-1985.01)

10. H.E. Ambassador Mrs. Lin Aili (1985.04-1988.03)

11. H.E. Ambassador Mr. Yu Lixuan (1988.05-1991.11)

12. H.E. Ambassador Mr. Qiao Zonghuai (1992.01-1993.09)

13. H.E. Ambassador Mr. Zheng Jinjiong (1993.09-1995.11)

14. H.E. Ambassador Mr. Wang Lian (1995.11-1998.10)

15. H.E. Ambassador Mr. Lu Xinhua (1998.11- 2002.02)

16. H.E. Ambassador Mr. Zhang Zhijian (2002.03-2006.05)

17. H.E. Ambassador Mrs. Ma Keqing (2006.05-2009.07)

18. H.E. Ambassador Mr. Huang Xing (2009.09-   )